Biaxial Discotic Gay-berne Mesogens and Biaxial Nematics
نویسندگان
چکیده
We investigate the thermotropic liquid crystal phases formed in a system of biaxial discotic mesogenic Gay-Berne particles with strong in-plane interactions when the attractive and repulsive biaxialities have the same or the opposite sign. We find that a biaxial nematic phase is obtained when the shape and well depth anisotropies have the same sign while we do not observe a columnar phase.
منابع مشابه
Do thermotropic biaxial nematics exist? A Monte Carlo study of biaxial Gay–Berne particles
We have investigated with extensive Monte Carlo simulations in the isothermal isobaric ensemble a system of N = 8192 elongated attractive–repulsive biaxial Gay–Berne (GB) particles. We have found a uniaxial and biaxial nematic and a biaxial orthogonal smectic phase in this thermotropic model system.
متن کاملDo thermotropic biaxial nematics exist? A Monte Carlo study of biaxial Gay-Berne particles, J. Chem. Phys., 113, 5971-5979 (2000)
We have investigated with extensive Monte Carlo simulations in the isothermal isobaric ensemble a system of N = 8192 elongated attractive–repulsive biaxial Gay–Berne (GB) particles. We have found a uniaxial and biaxial nematic and a biaxial orthogonal smectic phase in this thermotropic model system.
متن کاملPhase diagram of the uniaxial and biaxial soft-core Gay-Berne model.
Classical molecular dynamics simulations have been used to explore the phase diagrams for a family of attractive-repulsive soft-core Gay-Berne models [R. Berardi, C. Zannoni, J. S. Lintuvuori, and M. R. Wilson, J. Chem. Phys. 131, 174107 (2009)] and determine the effect of particle softness, i.e., of a moderately repulsive short-range interaction, on the order parameters and phase behaviour of ...
متن کاملMesogen polarity effects on biaxial nematics. Centrally located dipoles.
We investigate the phase organisation of thermotropic biaxial Gay-Berne (GB) mesogens yielding a biaxial nematic (Nb) phase upon endowing them with a central point dipole. We study the effects of changing the strength and orientation of the dipole on the phase behaviour, and in particular we examine, using molecular dynamics (MD) simulations, the possibility of improving the stability of the Nb...
متن کاملBiaxial nematic phase in model bent-core systems.
We determine the bifurcation phase diagrams with isotropic (I), uniaxial (N(U)) and biaxial (N(B)) nematic phases for model bent-core mesogens using Onsager-type theory. The molecules comprise two or three Gay-Berne interacting ellipsoids of uniaxial and biaxial shape and a transverse central dipole. The Landau point is found to turn into an I-N(B) line for the three-center model with a large d...
متن کامل